Cycloadditions in weakly and highly organized aqueous media : kinetic studies of cycloadditions in aqueous solvent mixtures and surfactant solutions

The study of kinetic medium effects in different solvents and solvent mixtures provides important information about intermolecular interactions that play a decisive role in controlling the rates of chemical reactions. Aqueous binary solvent mixtures are of particular interest. The properties of water are dominated by hydrogen-bond interactions. Furthermore, polar and apolar groups of dissolved molecules interact with water and the organic solvent component in distinctive ways. These features make chemical reactivity in mixed aqueous media a challenging topic. ...

Zie: Summary

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