Non-heme iron complexes as supramolecular oxidation catalysts.

In recent years non-heme iron complexes have been shown to be promising catalysts in the oxidation of alkanes and alkenes. These complexes are capable of mimicking iron oxygenases 1,2,3. As was mentioned in Chapter 1 the aim of the research described in this thesis was the investigation of non-heme iron complexes as catalysts for oxidation reactions like epoxidation and dihydroxylation. Investigations have been carried out to combine the substrate binding site of cyclodextrin with the catalyctic site of iron complexes in order to prepare a supramolecular catalyst with enhanced selectivity. ...

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