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(1995) Kimkes, Peter
Because of the failure of most of the main-chain conjugated aromatic azo polymers to dissolve in common organic solvents the processability of these polymers is difficult. The aim of this thesis is to synthesize (processable) main-chain conjugated aromatic azo polymers with interesting properties, by the oxidative coupling polymerization of a primary aromatic diamine in the copper0 cMoride/pyridine/dioxygen system. In addition, a kinetic study was performed to get more insight in the reaction-mechanism of this oxidative coupling polymerization.
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http://irs.ub.rug.nl/ppn/311797563 |
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